Issue 46, 2016
From the journal:

Chemical Communications

Spin-crossover complex encapsulation within a magnetic metal–organic framework†

Alexandre Abhervé,‡a   Thais Grancha,‡a   Jesús Ferrando-Soria,a   Miguel Clemente-León,*a   Eugenio Coronado,a   João C. Waerenborgh,b   Francesc Lloreta  and  Emilio Pardo*a  

* Corresponding authors

a Departament de Química Inorgànica/Instituto de Ciencia Molecular (ICMol), Universitat de València, 46980 Paterna, València, Spain
E-mail: miguel.clemente@uv.es, emilio.pardo@uv.es
Fax: +34 3543273
Tel: +34 3544442

b Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, 2695-066 Bobadela LRS, Portugal

Abstract

The solid-state incorporation of a mononuclear iron(III) complex within the pores of a magnetic 3D metal–organic framework (MOF) in a single crystal to single crystal process leads to the formation of a new hybrid material showing both a guest-dependent long-range magnetic ordering and a spin-crossover (SCO) behaviour.

Graphical abstract: Spin-crossover complex encapsulation within a magnetic metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C6CC03667H
Article type
Communication
Submitted
02 May 2016
Accepted
12 May 2016
First published
12 May 2016

Chem. Commun., 2016,52, 7360-7363

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Spin-crossover complex encapsulation within a magnetic metal–organic framework

A. Abhervé, T. Grancha, J. Ferrando-Soria, M. Clemente-León, E. Coronado, J. C. Waerenborgh, F. Lloret and E. Pardo, Chem. Commun., 2016, 52, 7360 DOI: 10.1039/C6CC03667H

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