Issue 53, 2016

N,N′-Dioxide/nickel(ii)-catalyzed asymmetric Diels–Alder reaction of cyclopentadiene with 2,3-dioxopyrrolidines and 2-alkenoyl pyridines

Abstract

A chiral N,N′-dioxide/Ni(OTf)2 complex-catalyzed asymmetric Diels–Alder reaction of cyclopentadiene with 2,3-dioxopyrrolidines and 2-alkenoyl pyridines has been achieved. The corresponding chiral bridged compounds were obtained in high yields with excellent dr and ee values (up to 97% yield, 95 : 5 dr and 97% ee).

Graphical abstract: N,N′-Dioxide/nickel(ii)-catalyzed asymmetric Diels–Alder reaction of cyclopentadiene with 2,3-dioxopyrrolidines and 2-alkenoyl pyridines

Supplementary files

Article information

Article type
Communication
Submitted
21 Apr 2016
Accepted
31 May 2016
First published
10 Jun 2016

Chem. Commun., 2016,52, 8255-8258

N,N′-Dioxide/nickel(II)-catalyzed asymmetric Diels–Alder reaction of cyclopentadiene with 2,3-dioxopyrrolidines and 2-alkenoyl pyridines

Y. Lu, Y. Zhou, L. Lin, H. Zheng, K. Fu, X. Liu and X. Feng, Chem. Commun., 2016, 52, 8255 DOI: 10.1039/C6CC03346F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements