Issue 56, 2016
From the journal:

Chemical Communications

A Zn based coordination polymer exhibiting long-lasting phosphorescence†

Javier Cepeda,*ab   Eider San Sebastian,a   Daniel Padro,c   Antonio Rodríguez-Diéguez,d   Jose A. García,e   Jesus M. Ugaldef  and  Jose M. Seco*a  

* Corresponding authors

a Applied Chemistry Department, Chemistry Faculty, University of the Basque Country (UPV/EHU), 20080 Donostia, Spain
E-mail: javier.cepeda@ehu.eus, josemanuel.seco@ehu.eus

b Polymer Science and Technology Department, Chemistry Faculty, University of the Basque Country (UPV/EHU), 20080 Donostia, Spain

c Nuclear Magnetic Resonance Platform, CIC BiomaGUNE, 20080 Donostia, Spain

d Inorganic Chemistry Department, Chemistry Faculty, University of Granada, 18071 Granada, Spain

e Applied Physics Department, Science and Technology Faculty, University of the Basque Country, UPV/EHU, 48940 Bilbao, Spain

f Kimika Fakultatea, Euskal Herriko Unibertsitatea (UPV/EHU) and Donostia International Physics Center (DIPC), P.K. 1072, 20080 Donostia, Euskadi, Spain

Abstract

A new Zn(II) based coordination polymer (CP) built by the cohesive pilling of 2D Shubnikov type layers is reported. This material exhibits time dependent multicoloured emission, part of which shows a persistent green phosphorescence visible for up to two seconds to the naked eye, which originates from multiple charge transfer mechanisms.

Graphical abstract: A Zn based coordination polymer exhibiting long-lasting phosphorescence

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Article information

DOI
https://doi.org/10.1039/C6CC03242G
Article type
Communication
Submitted
18 Apr 2016
Accepted
06 Jun 2016
First published
06 Jun 2016

Chem. Commun., 2016,52, 8671-8674

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A Zn based coordination polymer exhibiting long-lasting phosphorescence

J. Cepeda, E. S. Sebastian, D. Padro, A. Rodríguez-Diéguez, J. A. García, J. M. Ugalde and J. M. Seco, Chem. Commun., 2016, 52, 8671 DOI: 10.1039/C6CC03242G

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