Issue 36, 2016

Ethynide-stabilized high-nuclearity silver(i) sulfido molecular clusters assembled using organic sulfide precursors

Abstract

Inexpensive 1,1′-thiocarbonyldiimidazole and di(2-pyridyl) thionocarbonate have been used as respective sulfide precursors to assemble unprecedented high-nuclearity ethynide-stabilized silver(I) sulfido molecular clusters [Ag9S6@Ag36(C[triple bond, length as m-dash]CtBu)32(H2O)2] [Ag(imidazole)(CH3OH)(H2O)](BF4)2·8H2O·2CH3OH (1) and [Ag120S24(PhC[triple bond, length as m-dash]C)52Cl4(2-pyridone)10(H2O)8](H3O)4(SiF6)8(BF4)4·CH3OH·22H2O (2), the latter being the largest isolated silver(I) ethynide cluster reported to date.

Graphical abstract: Ethynide-stabilized high-nuclearity silver(i) sulfido molecular clusters assembled using organic sulfide precursors

Supplementary files

Article information

Article type
Communication
Submitted
29 Mar 2016
Accepted
05 Apr 2016
First published
06 Apr 2016

Chem. Commun., 2016,52, 6119-6122

Ethynide-stabilized high-nuclearity silver(I) sulfido molecular clusters assembled using organic sulfide precursors

Z. Chen, D. Y. S. Tam and T. C. W. Mak, Chem. Commun., 2016, 52, 6119 DOI: 10.1039/C6CC02631A

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