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Issue 40, 2016
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Oxygen insertion into boroles as a route to 1,2-oxaborines

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Abstract

The synthesis of 1,2-oxaborines is accomplished via the reaction of pentaarylboroles with N-methylmorpholine-N-oxide via a 1,1-insertion reaction. The aromatic nature of 1,2-oxaborines was evaluated by computing nuclear independent chemical shift (NICS) values. Collectively, the experimental and computational studies indicate the unsaturated central BOC4 ring has appreciable aromatic character.

Graphical abstract: Oxygen insertion into boroles as a route to 1,2-oxaborines

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Publication details

The article was received on 07 Mar 2016, accepted on 26 Mar 2016 and first published on 29 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC02040B
Citation: Chem. Commun., 2016,52, 6658-6661

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    Oxygen insertion into boroles as a route to 1,2-oxaborines

    S. Yruegas, D. C. Patterson and C. D. Martin, Chem. Commun., 2016, 52, 6658
    DOI: 10.1039/C6CC02040B

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