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Issue 40, 2016
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Oxygen insertion into boroles as a route to 1,2-oxaborines

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Abstract

The synthesis of 1,2-oxaborines is accomplished via the reaction of pentaarylboroles with N-methylmorpholine-N-oxide via a 1,1-insertion reaction. The aromatic nature of 1,2-oxaborines was evaluated by computing nuclear independent chemical shift (NICS) values. Collectively, the experimental and computational studies indicate the unsaturated central BOC4 ring has appreciable aromatic character.

Graphical abstract: Oxygen insertion into boroles as a route to 1,2-oxaborines

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Article information


Submitted
07 Mar 2016
Accepted
26 Mar 2016
First published
29 Mar 2016

Chem. Commun., 2016,52, 6658-6661
Article type
Communication

Oxygen insertion into boroles as a route to 1,2-oxaborines

S. Yruegas, D. C. Patterson and C. D. Martin, Chem. Commun., 2016, 52, 6658
DOI: 10.1039/C6CC02040B

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