Jump to main content
Jump to site search

Issue 36, 2016
Previous Article Next Article

Copper-catalyzed radical coupling of 1,3-dicarbonyl compounds with terminal alkenes for the synthesis of tetracarbonyl compounds

Author affiliations

Abstract

A novel and efficient copper-catalyzed radical cross-coupling of 1,3-dicarbonyl compounds with terminal alkenes for the synthesis of tetracarbonyl compounds with a quaternary carbon atom has been developed. Mechanistically, this transformation involves the construction of two C–C bonds and two C[double bond, length as m-dash]O bonds in a one-pot process. The reaction tolerates a wide range of functional groups and proceeds under mild conditions.

Graphical abstract: Copper-catalyzed radical coupling of 1,3-dicarbonyl compounds with terminal alkenes for the synthesis of tetracarbonyl compounds

Back to tab navigation

Supplementary files

Publication details

The article was received on 04 Mar 2016, accepted on 05 Apr 2016 and first published on 05 Apr 2016


Article type: Communication
DOI: 10.1039/C6CC01942K
Citation: Chem. Commun., 2016,52, 6127-6130

  •   Request permissions

    Copper-catalyzed radical coupling of 1,3-dicarbonyl compounds with terminal alkenes for the synthesis of tetracarbonyl compounds

    M. Zhang, M. Zhao, M. Chen, Z. Ren, Y. Wang and Z. Guan, Chem. Commun., 2016, 52, 6127
    DOI: 10.1039/C6CC01942K

Search articles by author

Spotlight

Advertisements