K+-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites

Wanmin Chen; Xiaoliang Tang; Wei Dou; Zhenghua Ju; Benhua Xu; Wenxuan Xu; Weisheng Liu

doi:10.1039/C6CC01938B

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K⁺-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(iii) complex crystallites†

Wanmin Chen,^a Xiaoliang Tang,*^a Wei Dou,^a Zhenghua Ju,^a Benhua Xu,^a Wenxuan Xu^a and Weisheng Liu*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province and State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, China
E-mail: tangxiaol@lzu.edu.cn, liuws@lzu.edu.cn

Abstract

A semi-rigid ligand could capture effectively Yb³⁺ ions to form a stable Yb³⁺ complex and provide a potential cavity to accommodate alkali metal ions. Only K⁺ ions could induce the Yb³⁺ complex to form a 1D coordination polymer and promote the in situ formation of an NIR membrane coated with bigger Yb³⁺ complex crystallites under mild conditions.

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Article information

DOI: https://doi.org/10.1039/C6CC01938B
Article type: Communication
Submitted: 04 Mar 2016
Accepted: 09 Mar 2016
First published: 09 Mar 2016

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Chem. Commun., 2016,52, 5124-5127

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K⁺-Induced in situ self-assembly of near-infrared luminescent membrane material armored with bigger Yb(III) complex crystallites

W. Chen, X. Tang, W. Dou, Z. Ju, B. Xu, W. Xu and W. Liu, Chem. Commun., 2016, 52, 5124 DOI: 10.1039/C6CC01938B

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Chemical Communications