Issue 29, 2016
From the journal:

Chemical Communications

Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane†

Zeguo Fang,a   Nawaf Al-Maharik,a   Alexandra M. Z. Slawin,a   Michael Bühla  and  David O'Hagan*a  

* Corresponding authors

a University of St Andrews, School of Chemistry and Centre for Biomolecular Sciences, North Haugh, St Andrews, Fife, UK
E-mail: do1@st-andrews.ac.uk
Fax: (0)1334 463800
Tel: (0)1334 467171

Abstract

The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

Graphical abstract: Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

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Article information

DOI
https://doi.org/10.1039/C6CC01348A
Article type
Communication
Submitted
12 Feb 2016
Accepted
10 Mar 2016
First published
11 Mar 2016

Chem. Commun., 2016,52, 5116-5119

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Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

Z. Fang, N. Al-Maharik, A. M. Z. Slawin, M. Bühl and D. O'Hagan, Chem. Commun., 2016, 52, 5116 DOI: 10.1039/C6CC01348A

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