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Issue 31, 2016
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Palladium-catalyzed C(sp3)–C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: efficient synthesis of functionalized benzyltrimethylsilanes

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Abstract

The first C(sp3)–C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.

Graphical abstract: Palladium-catalyzed C(sp3)–C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: efficient synthesis of functionalized benzyltrimethylsilanes

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Submitted
11 Feb 2016
Accepted
15 Mar 2016
First published
15 Mar 2016

Chem. Commun., 2016,52, 5425-5427
Article type
Communication

Palladium-catalyzed C(sp3)–C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: efficient synthesis of functionalized benzyltrimethylsilanes

G. Cai, Y. Huang, T. Du, S. Zhang, B. Yao and X. Li, Chem. Commun., 2016, 52, 5425
DOI: 10.1039/C6CC01312K

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