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Issue 26, 2016
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The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

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Abstract

A new class of well-defined activating supports for olefin polymerization was obtained via the surface organometallic chemistry approach. High activities in slurry polymerization of ethylene along with industrial-grade physical properties of the resulting polyethylene were obtained when these activators were combined with metallocene complexes in the presence of triisobutylaluminium.

Graphical abstract: The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

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Article information


Submitted
04 Jan 2016
Accepted
15 Feb 2016
First published
15 Feb 2016

Chem. Commun., 2016,52, 4776-4779
Article type
Communication

The design of a bipodal bis(pentafluorophenoxy)aluminate supported on silica as an activator for ethylene polymerization using surface organometallic chemistry

D. W. Sauter, N. Popoff, M. A. Bashir, K. C. Szeto, R. M. Gauvin, L. Delevoye, M. Taoufik and C. Boisson, Chem. Commun., 2016, 52, 4776
DOI: 10.1039/C6CC00060F

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