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Issue 19, 2016
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Photochemical water oxidation by cyclometalated iridium(III) complexes: a mechanistic insight

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Abstract

The proficiency of the cyclometalated iridium complexes [(η5-C5Me5)IrCl(L1)] (1), [(η5-C5Me5)IrCl(L2)] (2) and [(η5-C5Me5)IrCl(L3)] (3) has been examined towards photochemical water oxidation. The involvement of Ir(IV/V) in the catalytic process has been explored via CV, UV/vis, XPS spectroscopic studies and appreciable TON relative to the theoretical value of 1 from GC.

Graphical abstract: Photochemical water oxidation by cyclometalated iridium(iii) complexes: a mechanistic insight

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Publication details

The article was received on 23 Dec 2015, accepted on 02 Feb 2016 and first published on 03 Feb 2016


Article type: Communication
DOI: 10.1039/C5CC10520J
Chem. Commun., 2016,52, 3840-3843

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    Photochemical water oxidation by cyclometalated iridium(III) complexes: a mechanistic insight

    S. Mukhopadhyay, R. S. Singh, A. Biswas and D. S. Pandey, Chem. Commun., 2016, 52, 3840
    DOI: 10.1039/C5CC10520J

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