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Issue 13, 2016
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Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2

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Abstract

Cu3(BTC)2 is an efficient and reusable heterogeneous catalyst for the dehydrogenative coupling of silanes with alcohols. Activity data and CO adsorption suggest that Cu(II) and in situ generated Cu(I) are the active species. Other MOFs such as Fe(BTC), MIL-101(Cr) and UiO-66(Zr) are unable to promote this cross-coupling.

Graphical abstract: Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2

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Article information


Submitted
11 Dec 2015
Accepted
04 Jan 2016
First published
04 Jan 2016

Chem. Commun., 2016,52, 2725-2728
Article type
Communication

Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2

A. Dhakshinamoorthy, P. Concepcion and H. Garcia, Chem. Commun., 2016, 52, 2725
DOI: 10.1039/C5CC10216B

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