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Issue 6, 2016
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Pd-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates

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Abstract

A highly regio- and stereo-selective palladium-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates has been described. The method allows the synthesis of a variety of gem-difluoroallylated arenes with a tosyloxy group on the C[double bond, length as m-dash]C double bond, thus providing a good opportunity for down-stream transformations.

Graphical abstract: Pd-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates

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Publication details

The article was received on 09 Oct 2015, accepted on 18 Nov 2015 and first published on 18 Nov 2015


Article type: Communication
DOI: 10.1039/C5CC08394J
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Citation: Chem. Commun., 2016,52, 1238-1241
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    Pd-catalyzed gem-difluoroallylation of arylboronic acids with γ,γ-difluoroallylic acetates

    B. Zhang and X. Zhang, Chem. Commun., 2016, 52, 1238
    DOI: 10.1039/C5CC08394J

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