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Issue 8, 2016
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A zeolite CAN-type aluminoborate with gigantic 24-ring channels

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Abstract

A cancrinite type aluminoborate with gigantic 24-ring channels has been made under solvothermal conditions using Al(i-PrO)3 as the Al source and amines as the structure directing agents. Its framework is alternately constructed from B5O10 clusters and AlO4 units, no Al–O–Al linkages exist in the structure. Notably, the wall of the 24-ring channels has odd 11-ring windows, resulting in an unprecedented 3D intersecting channel system.

Graphical abstract: A zeolite CAN-type aluminoborate with gigantic 24-ring channels

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Publication details

The article was received on 30 Sep 2015, accepted on 26 Nov 2015 and first published on 26 Nov 2015


Article type: Communication
DOI: 10.1039/C5CC08164E
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Citation: Chem. Commun., 2016,52, 1729-1732

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    A zeolite CAN-type aluminoborate with gigantic 24-ring channels

    G. Cao, Q. Wei, J. Cheng, L. Cheng and G. Yang, Chem. Commun., 2016, 52, 1729
    DOI: 10.1039/C5CC08164E

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