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Issue 99, 2015
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Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

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Abstract

The stereospecific hydrolysis of bulky aminophosphine boranes is reported for the first time. The resulting phosphinous acid boranes, upon activation, undergo stereospecific nucleophilic substitution reaction at the phosphorous center with amine nucleophiles. The combination of these two processes provides a novel access to bulky P*-ligands.

Graphical abstract: Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

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Publication details

The article was received on 07 Sep 2015, accepted on 29 Sep 2015 and first published on 02 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC07504A
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Citation: Chem. Commun., 2015,51, 17548-17551
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    Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

    S. Orgué, A. Flores-Gaspar, M. Biosca, O. Pàmies, M. Diéguez, A. Riera and X. Verdaguer, Chem. Commun., 2015, 51, 17548
    DOI: 10.1039/C5CC07504A

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