Issue 97, 2015
From the journal:

Chemical Communications

Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(iii) complex†

Yukun Zhao,a   Junqi Lin,a   Yongdong Liu,a   Baochun Ma,a   Yong Ding*ab  and  Mindong Chenb  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
E-mail: dingyong1@lzu.edu.cn

b Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control (AEMPC), School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, China

Abstract

A mononuclear Co complex, [CoIII(DPK·OH)2]Cl (DPK = di(2-pyridyl)ketone), was synthesized and reported as a stable catalyst in visible light-driven water oxidation. The optimum turnover number (TON) of complex 1 is 1610, which, to the best of our knowledge, is the largest TON among metal–organic complexes for photocatalytic water oxidation.

Graphical abstract: Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(iii) complex

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Article information

DOI
https://doi.org/10.1039/C5CC07448G
Article type
Communication
Submitted
04 Sep 2015
Accepted
25 Sep 2015
First published
25 Sep 2015

Chem. Commun., 2015,51, 17309-17312

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Efficient light-driven water oxidation catalyzed by a mononuclear cobalt(III) complex

Y. Zhao, J. Lin, Y. Liu, B. Ma, Y. Ding and M. Chen, Chem. Commun., 2015, 51, 17309 DOI: 10.1039/C5CC07448G

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