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Issue 95, 2015
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Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

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Abstract

A novel terphenylphosphine PMe2ArDipp2 (1) (Dipp = 2,6-iPr2C6H3) forms stable Pt(0) complexes with ethene and 3,3-dimethylbut-1-ene that behave as sources of the reactive Pt(PMe2ArDipp2) fragment. The complexes are efficient catalysts for the selective hydrosilylation of terminal alkynes.

Graphical abstract: Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

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Publication details

The article was received on 03 Sep 2015, accepted on 25 Sep 2015 and first published on 28 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07308A
Chem. Commun., 2015,51, 17008-17011

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    Platinum(0) olefin complexes of a bulky terphenylphosphine ligand. Synthetic, structural and reactivity studies

    L. Ortega-Moreno, R. Peloso, C. Maya, A. Suárez and E. Carmona, Chem. Commun., 2015, 51, 17008
    DOI: 10.1039/C5CC07308A

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