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Issue 96, 2015
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Alternating chiral selectivity of aldol reactions under the confined space of mesoporous silica

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Abstract

The chiral selectivities were altered and high diastereo- and enantio-selectivities of the products were obtained in water medium without adding acid co-catalysts when a primary–tertiary diamine catalyst was immobilized on mesoporous SBA-15 to form a recyclable catalyst for the direct asymmetric aldol reaction of cyclohexanone with p-nitrobenzaldehyde.

Graphical abstract: Alternating chiral selectivity of aldol reactions under the confined space of mesoporous silica

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The article was received on 29 Aug 2015, accepted on 28 Sep 2015 and first published on 29 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07255G
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Chem. Commun., 2015,51, 17116-17119

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    Alternating chiral selectivity of aldol reactions under the confined space of mesoporous silica

    C. Yeh, Y. Sun, S. Huang, Y. Tsai and S. Cheng, Chem. Commun., 2015, 51, 17116
    DOI: 10.1039/C5CC07255G

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