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Issue 88, 2015
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Synthesis of cyclic diborenes with unprecedented cis-configuration

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Abstract

The first examples of cis-configured diborenes – and the first cyclic diborenes – are isolated by taking advantage of stabilisation by chelating diphosphine ligands. The diborenes are prepared by a convenient one-pot reductive procedure that circumvents the need for a pre-formed base-adduct of the boron-containing precursor.

Graphical abstract: Synthesis of cyclic diborenes with unprecedented cis-configuration

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Publication details

The article was received on 24 Aug 2015, accepted on 04 Sep 2015 and first published on 04 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC07103H
Chem. Commun., 2015,51, 15917-15920

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    Synthesis of cyclic diborenes with unprecedented cis-configuration

    P. Bissinger, H. Braunschweig, M. A. Celik, C. Claes, R. D. Dewhurst, S. Endres, H. Kelch, T. Kramer, I. Krummenacher and C. Schneider, Chem. Commun., 2015, 51, 15917
    DOI: 10.1039/C5CC07103H

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