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Issue 100, 2015
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Uniaxial magnetic anisotropy of square-planar chromium(ii) complexes revealed by magnetic and HF-EPR studies

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Abstract

Two mononuclear square-planar Cr(II) complexes are reported, exhibiting field-induced slow magnetic relaxation. The axial zero-field splitting parameter was unambiguously determined by both a high-frequency/field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements. This result represents the first observed single-molecule-magnet behavior in the square planar coordination geometry of any metal ions.

Graphical abstract: Uniaxial magnetic anisotropy of square-planar chromium(ii) complexes revealed by magnetic and HF-EPR studies

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Article information


Submitted
20 Aug 2015
Accepted
12 Nov 2015
First published
12 Nov 2015

This article is Open Access

Chem. Commun., 2015,51, 17688-17691
Article type
Communication
Author version available

Uniaxial magnetic anisotropy of square-planar chromium(II) complexes revealed by magnetic and HF-EPR studies

Y. Deng, T. Han, Z. Wang, Z. Ouyang, B. Yin, Z. Zheng, J. Krzystek and Y. Zheng, Chem. Commun., 2015, 51, 17688
DOI: 10.1039/C5CC07025B

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