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Issue 100, 2015
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Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

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Abstract

An efficient and general copper(I)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

Graphical abstract: Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

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Supplementary files

Article information


Submitted
07 Aug 2015
Accepted
12 Oct 2015
First published
22 Oct 2015

This article is Open Access

Chem. Commun., 2015,51, 17684-17687
Article type
Communication

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

A. López, A. Parra, C. Jarava-Barrera and M. Tortosa, Chem. Commun., 2015, 51, 17684 DOI: 10.1039/C5CC06653K

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