Issue 100, 2015

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

Abstract

An efficient and general copper(I)-catalyzed silylation of p-quinone-methides is described. Non-symmetric dibenzylic silanes are obtained in high yields under mild reaction conditions. These compounds can be used as bench-stable benzylic carbanion precursors.

Graphical abstract: Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2015
Accepted
12 Oct 2015
First published
22 Oct 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 17684-17687

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes

A. López, A. Parra, C. Jarava-Barrera and M. Tortosa, Chem. Commun., 2015, 51, 17684 DOI: 10.1039/C5CC06653K

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