SCHEDULED MAINTENANCE
The mechanism of the phase transition of 1-phenyl-3-trifluoromethyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl (1), the first reported triazinyl radical to present such a feature, is unveiled. In so doing, we identify the key ingredients that are crucial to enable the phase transition in this family of radicals, and how those can be exploited by a rational design of the spin-carrying units.
M. Fumanal, S. Vela, J. J. Novoa and J. Ribas-Arino, Chem. Commun., 2015, 51, 15776 DOI: 10.1039/C5CC06288H
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