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Issue 96, 2015
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TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination of 2,3-allenyl perfluoroalkyl ketones

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Abstract

A unique TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination reaction of easily available n-perfluoroalkyl allenones in the presence of H2O providing furanyl perfluoroalkyl ketones has been developed. The 18O-labelling experiments confirmed that the oxygen atom of the carbonyl group in the final products originates from water.

Graphical abstract: TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination of 2,3-allenyl perfluoroalkyl ketones

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Publication details

The article was received on 22 Jul 2015, accepted on 21 Sep 2015 and first published on 22 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC06111C
Chem. Commun., 2015,51, 17112-17115

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    TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination of 2,3-allenyl perfluoroalkyl ketones

    C. Xue, X. Huang, S. Wu, J. Zhou, J. Dai, C. Fu and S. Ma, Chem. Commun., 2015, 51, 17112
    DOI: 10.1039/C5CC06111C

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