Issue 84, 2015
From the journal:

Chemical Communications

Mechanism-based design of labile precursors for chromium(i) chemistry†

Eser S. Akturk,a   Glenn P. A. Yapa  and  Klaus H. Theopold*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA
E-mail: theopold@udel.educ

Abstract

Dinitrogen complexes of the type TpR,RCr–N2–CrTpR,R are not the most labile precursors for Cr(I) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – TptBu,MeCr(η2-C2(SiMe3)2) – proved to be much more reactive.

Graphical abstract: Mechanism-based design of labile precursors for chromium(i) chemistry

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Article information

DOI
https://doi.org/10.1039/C5CC05993C
Article type
Communication
Submitted
18 Jul 2015
Accepted
27 Aug 2015
First published
27 Aug 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 15402-15405

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Mechanism-based design of labile precursors for chromium(I) chemistry

E. S. Akturk, G. P. A. Yap and K. H. Theopold, Chem. Commun., 2015, 51, 15402 DOI: 10.1039/C5CC05993C

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