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Issue 84, 2015
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Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters

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Abstract

Gold-catalyzed synthesis of buta-1,3-dien-2-yl esters by the reaction of propargyl esters with vinylazides is described; the reaction mechanism is postulated to involve a vinyl attack of vinylazides at alkenyl gold carbenes.

Graphical abstract: Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters

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The article was received on 17 Jul 2015, accepted on 01 Sep 2015 and first published on 01 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC05945C
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Citation: Chem. Commun., 2015,51, 15462-15464

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    Gold-catalyzed reactions of propargylic esters with vinylazides for the synthesis of Z- or E-configured buta-1,3-dien-2-yl esters

    S. B. Wagh and R. Liu, Chem. Commun., 2015, 51, 15462
    DOI: 10.1039/C5CC05945C

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