Issue 84, 2015

Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

Abstract

Na2MoO2−δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.

Graphical abstract: Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

Supplementary files

Article information

Article type
Communication
Submitted
02 Jul 2015
Accepted
03 Sep 2015
First published
03 Sep 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 15469-15471

Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

H. Ishikawa, I. Munaò, B. E. Bode, Z. Hiroi and P. Lightfoot, Chem. Commun., 2015, 51, 15469 DOI: 10.1039/C5CC05446J

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