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Issue 84, 2015
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Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

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Abstract

Na2MoO2−δF4+δ (δ ∼ 0.08) displays a unique variant of the perovskite structure, with simultaneous (Na,vacancy) ordering on the A-site, (Na,Mo) ordering on the B-site, (O,F) ordering on the anion site and an unusual NaNbO3-like octahedral tilt system.

Graphical abstract: Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

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Supplementary files

Article information


Submitted
02 Jul 2015
Accepted
03 Sep 2015
First published
03 Sep 2015

This article is Open Access

Chem. Commun., 2015,51, 15469-15471
Article type
Communication
Author version available

Na2MoO2−δF4+δ – a perovskite with a unique combination of atomic orderings and octahedral tilts

H. Ishikawa, I. Munaò, B. E. Bode, Z. Hiroi and P. Lightfoot, Chem. Commun., 2015, 51, 15469
DOI: 10.1039/C5CC05446J

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