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Issue 64, 2015
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Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement

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Abstract

Mixing of metallocyclic trimers and tetramers in an exact 1 : 1.5 stoichiometry provided new supramolecular triangles in quantitative yields. Characterization of the new hetero-nuclear metallomacrocycles was achieved by 1H, 2D-COSY, 2D-NOESY, and 13C NMR spectroscopy, along with ESI and TWIM mass spectrometry. Gradient tandem MS (gMS2) provided insight into the stabilities of the binuclear structures.

Graphical abstract: Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement

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Publication details

The article was received on 18 Jun 2015, accepted on 03 Jul 2015 and first published on 03 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC05048K
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Chem. Commun., 2015,51, 12851-12854

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    Multicomponent reassembly of terpyridine-based materials: quantitative metallomacrocyclic rearrangement

    R. Sarkar, Z. Guo, J. Li, T. N. Burai, C. Moorefield, C. Wesdemiotis and G. R. Newkome, Chem. Commun., 2015, 51, 12851
    DOI: 10.1039/C5CC05048K

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