Issue 76, 2015

Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

Abstract

Novel organocobalt complexes featuring weak C–CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of α-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction.

Graphical abstract: Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

Supplementary files

Article information

Article type
Communication
Submitted
08 Jun 2015
Accepted
17 Jul 2015
First published
05 Aug 2015

Chem. Commun., 2015,51, 14334-14337

Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

J. Demarteau, A. Kermagoret, I. German, D. Cordella, K. Robeyns, J. De Winter, P. Gerbaux, C. Jérôme, A. Debuigne and C. Detrembleur, Chem. Commun., 2015, 51, 14334 DOI: 10.1039/C5CC04714E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements