Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 70, 2015
Previous Article Next Article

Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands

Author affiliations

Abstract

An organometallic Au13 cluster having two σ-bonded acetylide ligands was synthesized and its structure was determined by X-ray crystallography. Absorption spectral studies indicated the presence of electronic coupling between the superatomic Au13 core and the acetylide π-orbitals, which was supported by theoretical considerations.

Graphical abstract: Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands

Back to tab navigation

Supplementary files

Publication details

The article was received on 26 May 2015, accepted on 30 Jun 2015 and first published on 30 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04312C
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2015,51, 13519-13522

  •   Request permissions

    Cluster–π electronic interaction in a superatomic Au13 cluster bearing σ-bonded acetylide ligands

    M. Sugiuchi, Y. Shichibu, T. Nakanishi, Y. Hasegawa and K. Konishi, Chem. Commun., 2015, 51, 13519
    DOI: 10.1039/C5CC04312C

Search articles by author

Spotlight

Advertisements