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Issue 75, 2015
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An iodine(iii) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones

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Abstract

An iodine(III)-mediated, group-selective oxidative rearrangement of β,β-diarylenamines to α-amino ketones has been accomplished with excellent yield. The developed reaction involves the initial oxidation of enamine to an α-acyloxyimine intermediate and concomitant semipinacol rearrangement.

Graphical abstract: An iodine(iii) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones

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Publication details

The article was received on 24 May 2015, accepted on 30 Jul 2015 and first published on 30 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04265H
Chem. Commun., 2015,51, 14203-14206

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    An iodine(III) mediated oxidative rearrangement of enamines: efficient synthesis of α-amino ketones

    D. Yadagiri and P. Anbarasan, Chem. Commun., 2015, 51, 14203
    DOI: 10.1039/C5CC04265H

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