Issue 67, 2015

Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors

Abstract

A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

Graphical abstract: Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors

Supplementary files

Article information

Article type
Communication
Submitted
22 May 2015
Accepted
01 Jul 2015
First published
06 Jul 2015

Chem. Commun., 2015,51, 13178-13180

Author version available

Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors

X. Shi, S. Lee, M. Son, B. Zheng, J. Chang, L. Jing, K. Huang, D. Kim and C. Chi, Chem. Commun., 2015, 51, 13178 DOI: 10.1039/C5CC04243G

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