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Issue 59, 2015
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Double CO2 activation by 14-electron η8-permethylpentalene titanium dialkyl complexes

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Abstract

The novel 14 electron species η8-Pn*TiR2 (Pn* = C8Me6; R = Me, CH2Ph) have been synthesised and spectroscopically and structurally characterised. Subsequent reaction with CO2 leads to the activation and double insertion of CO2 into both Ti–alkyl bonds to form the electronically saturated η8-Pn*Ti(κ2-O2CR)2 (R = Me, CH2Ph) complexes.

Graphical abstract: Double CO2 activation by 14-electron η8-permethylpentalene titanium dialkyl complexes

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The article was received on 18 May 2015, accepted on 18 Jun 2015 and first published on 25 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04094A
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Chem. Commun., 2015,51, 11856-11859

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    Double CO2 activation by 14-electron η8-permethylpentalene titanium dialkyl complexes

    R. T. Cooper, F. M. Chadwick, A. E. Ashley and D. O'Hare, Chem. Commun., 2015, 51, 11856
    DOI: 10.1039/C5CC04094A

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