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Issue 67, 2015
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Dual template effect of supercritical CO2 in ionic liquid to fabricate a highly mesoporous cobalt metal–organic framework

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Abstract

A hierarchical meso- and microporous metal–organic framework (MOF) was facilely fabricated in an ionic liquid (IL)/supercritical CO2 (SC CO2)/surfactant emulsion system. Notably, CO2 exerts a dual effect during the synthesis; that is, CO2 droplets act as a template for the cores of nanospheres while CO2-swollen micelles induce mesopores on nanospheres.

Graphical abstract: Dual template effect of supercritical CO2 in ionic liquid to fabricate a highly mesoporous cobalt metal–organic framework

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Publication details

The article was received on 14 May 2015, accepted on 09 Jul 2015 and first published on 10 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04009D
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Citation: Chem. Commun., 2015,51, 13197-13200

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    Dual template effect of supercritical CO2 in ionic liquid to fabricate a highly mesoporous cobalt metal–organic framework

    H. Yu, D. Xu and Q. Xu, Chem. Commun., 2015, 51, 13197
    DOI: 10.1039/C5CC04009D

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