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Issue 77, 2015
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Pt(II)-Catalyzed photosynthesis for H2 evolution cycling between singly and triply reduced species

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Abstract

A PtCl2(bpy) derivative tethered to two viologen (MV2+) moieties drives photochemical H2 evolution via forming a three-electron-reduced species possessing a bpy˙-based (or MV0-based) reducing equivalent. Such species can only form after one electron reduction of both the MV2+ sites because of rapid intramolecular electron transfer from bpy˙ to MV2+.

Graphical abstract: Pt(ii)-Catalyzed photosynthesis for H2 evolution cycling between singly and triply reduced species

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Publication details

The article was received on 28 Apr 2015, accepted on 04 Aug 2015 and first published on 04 Aug 2015


Article type: Communication
DOI: 10.1039/C5CC03558A
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Citation: Chem. Commun., 2015,51, 14516-14519

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    Pt(II)-Catalyzed photosynthesis for H2 evolution cycling between singly and triply reduced species

    K. Yamamoto, K. Kitamoto, K. Yamauchi and K. Sakai, Chem. Commun., 2015, 51, 14516
    DOI: 10.1039/C5CC03558A

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