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Issue 52, 2015
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Photoinduced reductive perfluoroalkylation of phosphine oxides: synthesis of P-perfluoroalkylated phosphines using TMDPO and perfluoroalkyl iodides

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Abstract

A photoinduced reaction between TMDPO (diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide) and perfluoroalkyl iodides successfully affords P-(perfluoroalkyl)diphenylphosphines as promising ligands for recyclable catalysts. Interestingly, the perfluoroalkylation reaction involves the reduction of phosphorus(V) compounds to phosphorus(III) species. The advantages of the present reaction include the use of an air-stable phosphorus source and good yields of P-perfluoroalkylphosphines in short reaction times.

Graphical abstract: Photoinduced reductive perfluoroalkylation of phosphine oxides: synthesis of P-perfluoroalkylated phosphines using TMDPO and perfluoroalkyl iodides

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Publication details

The article was received on 24 Apr 2015, accepted on 15 May 2015 and first published on 18 May 2015


Article type: Communication
DOI: 10.1039/C5CC03427B
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Chem. Commun., 2015,51, 10385-10388

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    Photoinduced reductive perfluoroalkylation of phosphine oxides: synthesis of P-perfluoroalkylated phosphines using TMDPO and perfluoroalkyl iodides

    Y. Sato, S. Kawaguchi and A. Ogawa, Chem. Commun., 2015, 51, 10385
    DOI: 10.1039/C5CC03427B

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