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Issue 48, 2015
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A bimetallic iridium(II) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

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Abstract

A new Ir(II) complex [{Ir(μ-κCNHC6Dipp-IDipp)(H)}2][BF4]2 has been prepared and fully characterised. This complex acts as a catalyst for the hydroalkynylation of imines according to an unprecedented diiridium-mediated mechanism.

Graphical abstract: A bimetallic iridium(ii) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

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Publication details

The article was received on 22 Apr 2015, accepted on 08 May 2015 and first published on 08 May 2015


Article type: Communication
DOI: 10.1039/C5CC03296B
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Citation: Chem. Commun., 2015,51, 9860-9863

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    A bimetallic iridium(II) catalyst: [{Ir(IDipp)(H)}2][BF4]2 (IDipp = 1,3-bis(2,6-diisopropylphenylimidazol-2-ylidene))

    L. Rubio-Pérez, M. Iglesias, J. Munárriz, V. Polo, P. J. Sanz Miguel, J. J. Pérez-Torrente and L. A. Oro, Chem. Commun., 2015, 51, 9860
    DOI: 10.1039/C5CC03296B

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