Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 44, 2015
Previous Article Next Article

Unprecedented χ isomers of single-side triol-functionalized Anderson polyoxometalates and their proton-controlled isomer transformation

Author affiliations

Abstract

The μ2-O atom in Anderson polyoxometalates was regioselectively activated by the introduction of protons, which, upon functionalization with triol ligands, could afford a series of unique χ isomers of the organically-derived Anderson cluster {[RCC(CH2O)3]MMo6O18(OH)3}3−. Herein proton-controlled isomer transformation between the δ and χ isomer was observed by using the fingerprint region in the IR spectra and 13C NMR spectra.

Graphical abstract: Unprecedented χ isomers of single-side triol-functionalized Anderson polyoxometalates and their proton-controlled isomer transformation

Back to tab navigation

Supplementary files

Article information


Submitted
10 Apr 2015
Accepted
22 Apr 2015
First published
22 Apr 2015

Chem. Commun., 2015,51, 9097-9100
Article type
Communication

Unprecedented χ isomers of single-side triol-functionalized Anderson polyoxometalates and their proton-controlled isomer transformation

J. Zhang, Z. Liu, Y. Huang, J. zhang, J. Hao and Y. Wei, Chem. Commun., 2015, 51, 9097
DOI: 10.1039/C5CC02947C

Social activity

Search articles by author

Spotlight

Advertisements