Issue 41, 2015
From the journal:

Chemical Communications

Estimation of bonding nature using diamagnetic susceptibility†

Keisuke Tomiyasu,*a   Toyoto Satob  and  Shin-ichi Orimobc  

* Corresponding authors

a Department of Physics, Tohoku University, Aoba, Sendai 980-8578, Japan
E-mail: tomiyasu@m.tohoku.ac.jp

b Institute for Materials Research, Tohoku University, Aoba, Sendai 980-8577, Japan

c WPI-Advanced Institute for Materials Research, Tohoku University, Aoba, Sendai 980-8577, Japan

Abstract

A chemical bond includes both covalent and ionic characteristics. We develop an experimental method to estimate the degree of each contribution based on magnetic susceptibility measurements, in which Pascal's scheme for Larmor diamagnetism is combined with electronegativity. The applicability to metal hydrides is also shown.

Graphical abstract: Estimation of bonding nature using diamagnetic susceptibility

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Article information

DOI
https://doi.org/10.1039/C5CC02351C
Article type
Communication
Submitted
20 Mar 2015
Accepted
15 Apr 2015
First published
24 Apr 2015

Chem. Commun., 2015,51, 8691-8694

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Estimation of bonding nature using diamagnetic susceptibility

K. Tomiyasu, T. Sato and S. Orimo, Chem. Commun., 2015, 51, 8691 DOI: 10.1039/C5CC02351C

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