Issue 41, 2015

Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

Abstract

An imine-based 2D polymer side-functionalized with o-hydroxyl group was designed in regard to its potential ability to serve as a chelating agent and synthesized on a highly oriented pyrolytic graphite surface with a relatively low annealing temperature. When annealed to a higher temperature the o-hydroxyl group reacts further with the imine group, leading to the formation of oxazoline, which causes significant distortion to the network. The formation of oxazoline was further confirmed by ATR-FTIR.

Graphical abstract: Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

Supplementary files

Article information

Article type
Communication
Submitted
17 Mar 2015
Accepted
10 Apr 2015
First published
13 Apr 2015

Chem. Commun., 2015,51, 8664-8667

Author version available

Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

L. Xu, L. Cao, Z. Guo, Z. Zha and S. Lei, Chem. Commun., 2015, 51, 8664 DOI: 10.1039/C5CC02232K

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