Issue 37, 2015
From the journal:

Chemical Communications

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent†

Akira Yoshimura,*a   Khiem C. Nguyen,a   Scott C. Klasen,a   Akio Saito,b   Victor N. Nemykina  and  Viktor V. Zhdankin*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, MN 55812, USA
E-mail: vzhdanki@d.umn.edu, ayoshimu@d.umn.edu
Fax: +1 218-726-7394

b Division of Applied Chemistry, Institute of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA–OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA–OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

Graphical abstract: Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

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Article information

DOI
https://doi.org/10.1039/C5CC02009C
Article type
Communication
Submitted
10 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

Chem. Commun., 2015,51, 7835-7838

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Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

A. Yoshimura, K. C. Nguyen, S. C. Klasen, A. Saito, V. N. Nemykin and V. V. Zhdankin, Chem. Commun., 2015, 51, 7835 DOI: 10.1039/C5CC02009C

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