Regio- and stereoselective hydrocyanation under nickel catalysis is described. This report shows that allenyl C–C double bonds are discriminated and converted to the corresponding carbonitriles as a single product. The key functionalities for achieving high regio- and stereocontrol are aryl and cyclopropyl groups in the substrates.
S. Arai, H. Hori, Y. Amako and A. Nishida, Chem. Commun., 2015, 51, 7493 DOI: 10.1039/C5CC01899D
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