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Issue 48, 2015
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Probing CuI in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy

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Abstract

Metal-to-ligand charge transfer excitations in CuI X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectroscopic parameters.

Graphical abstract: Probing CuI in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy

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Publication details

The article was received on 03 Mar 2015, accepted on 13 May 2015 and first published on 21 May 2015


Article type: Communication
DOI: 10.1039/C5CC01827G
Chem. Commun., 2015,51, 9864-9867

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    Probing CuI in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy

    R. C. Walroth, J. W. H. Uebler and K. M. Lancaster, Chem. Commun., 2015, 51, 9864
    DOI: 10.1039/C5CC01827G

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