Issue 36, 2015
From the journal:

Chemical Communications

Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes†

Qiu Sun,a   Yaorong Wang,a   Dan Yuan,*a   Yingming Yao*a  and  Qi Shena  

* Corresponding authors

a Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Dushu Lake Campus, Soochow University, Suzhou 215123, People's Republic of China
E-mail: yuandan@suda.edu.cn, yaoym@suda.edu.cn
Fax: +86 512 65880305
Tel: +86 512 65882806

Abstract

An in situ generated cationic zirconium complex stabilized by an n-butylamine-bridged bis(phenolato) ligand has been developed to catalyse hydroamination reactions of secondary amines, which is the first example of group 4 metal based catalysts capable of mediating intermolecular hydroamination reactions of N-aryl/alkyl amines.

Graphical abstract: Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes

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Article information

DOI
https://doi.org/10.1039/C5CC01780G
Article type
Communication
Submitted
02 Mar 2015
Accepted
27 Mar 2015
First published
27 Mar 2015

Chem. Commun., 2015,51, 7633-7636

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Zirconium catalysed intermolecular hydroamination reactions of secondary amines with alkynes

Q. Sun, Y. Wang, D. Yuan, Y. Yao and Q. Shen, Chem. Commun., 2015, 51, 7633 DOI: 10.1039/C5CC01780G

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