Issue 39, 2015
From the journal:

Chemical Communications

First evidence of light-induced spin transition in molybdenum(iv)†

N. Bridonneau,a   J. Long,a   J.-L. Cantin,b   J. von Bardeleben,b   S. Pillet,c   E.-E. Bendeif,c   D. Aravena, ORCID logo d   E. Ruizd  and  V. Marvaud*a  

* Corresponding authors

a IPCM-CNRS-UMR-8232, UPMC-Univ. Paris 6, cc 42, 4 place Jussieu, 75252 Paris Cedex 05, France
E-mail: valerie.marvaud@upmc.fr
Fax: +33 (0)1 44 27 38 41
Tel: +33 (0)1 44 27 32 77

b INSP – CNRS UMR-7588, UPMC- Univ. Paris 6, 4 place Jussieu, 75252 Paris Cedex 05, France

c CRM2, UMR CNRS 7036, Institut Jean Barriol, Université de Lorraine, 54506 Vandoeuvre-les-Nancy, France

d Departament de Química Inorgànica and Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, E-08028 Barcelona, Spain

Abstract

Photo-induced spin transition in a molybdenum–zinc complex has been evidenced and fully characterized by Squid magnetometry and several spectroscopies performed under irradiation (IR, EPR, etc.). The phenomenon has been confirmed by X-ray diffraction and DFT calculations yielding a Light-Induced Excited Spin State Trapping Effect (LIESST) on a 4d transition metal ion.

Graphical abstract: First evidence of light-induced spin transition in molybdenum(iv)

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Article information

DOI
https://doi.org/10.1039/C5CC01714A
Article type
Communication
Submitted
26 Feb 2015
Accepted
25 Mar 2015
First published
25 Mar 2015

Chem. Commun., 2015,51, 8229-8232

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First evidence of light-induced spin transition in molybdenum(IV)

N. Bridonneau, J. Long, J.-L. Cantin, J. von Bardeleben, S. Pillet, E.-E. Bendeif, D. Aravena, E. Ruiz and V. Marvaud, Chem. Commun., 2015, 51, 8229 DOI: 10.1039/C5CC01714A

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