Issue 54, 2015

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

Abstract

A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe–Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented.

Graphical abstract: Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

Supplementary files

Article information

Article type
Communication
Submitted
21 Feb 2015
Accepted
28 May 2015
First published
28 May 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 10949-10952

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

L. Hettmanczyk, S. Manck, C. Hoyer, S. Hohloch and B. Sarkar, Chem. Commun., 2015, 51, 10949 DOI: 10.1039/C5CC01578B

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