Issue 30, 2015
From the journal:

Chemical Communications

Direct fluorination of styrenes†

Qian Shaoa  and  Yong Huang*a  

* Corresponding authors

a Key Laboratory of Chemical Genomics, Peking University, Shenzhen Graduate School, Shenzhen, 518055 China
E-mail: huangyong@pkusz.edu.cn

Abstract

We have developed a practical method to synthesize fluorostyrene compounds. A mild and regioselective mono-fluorination reaction occurred smoothly for various di- and trisubstituted styrenes in the presence of RuCl3 and N-fluorobenzenesulfonimide (NFSI). A tandem alkyne hydroarylation–olefin fluorination reaction was also developed using an Au catalyst.

Graphical abstract: Direct fluorination of styrenes

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Article information

DOI
https://doi.org/10.1039/C5CC01407G
Article type
Communication
Submitted
14 Feb 2015
Accepted
05 Mar 2015
First published
06 Mar 2015

Chem. Commun., 2015,51, 6584-6586

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Direct fluorination of styrenes

Q. Shao and Y. Huang, Chem. Commun., 2015, 51, 6584 DOI: 10.1039/C5CC01407G

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