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Issue 31, 2015
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Two-coordinate hydrido-germylenes

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Abstract

The first structurally characterised two-coordinate hydrido-germylenes, :Ge(H)L (L = –N(Ar){Si(OBut3)}, Ar = C6H2{C(H)Ph2}2R-2,6,4; R = Pri (tBuOL), Me (tBuOL*)), have been prepared, and their dimerisation shown to be thermodynamically unfavourable, largely due to the extreme steric bulk of their amide ligands.

Graphical abstract: Two-coordinate hydrido-germylenes

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Submitted
12 Feb 2015
Accepted
16 Mar 2015
First published
17 Mar 2015

Chem. Commun., 2015,51, 6854-6857
Article type
Communication

Two-coordinate hydrido-germylenes

T. J. Hadlington, B. Schwarze, E. I. Izgorodina and C. Jones, Chem. Commun., 2015, 51, 6854
DOI: 10.1039/C5CC01314C

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