Issue 47, 2015
From the journal:

Chemical Communications

A new lithium-rich anti-spinel in Li–O–Br system

J. Zhang,*a   J. Zhu,b   L. Wangb  and  Y. Zhao*b  

* Corresponding authors

a Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, USA
E-mail: jzhang@lanl.gov

b High Pressure Science and Engineering Center and Department of Physics and Astronomy, University of Nevada, Las Vegas, USA
E-mail: Yusheng.Zhao@unlv.edu

Abstract

In spinel-type materials currently known, the divalent anions are arranged in a closed-pack lattice and cations of various valences occupy some or all of the tetrahedral and octahedral sites. We report here the first discovery of an “electronically inverted” anti-spinel. The new material, crystallized in a defect spinel structure, was obtained from the dehydration of Li5Br(OH)4 under moderate pressure and temperature conditions.

Graphical abstract: A new lithium-rich anti-spinel in Li–O–Br system

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Article information

DOI
https://doi.org/10.1039/C5CC01109D
Article type
Communication
Submitted
05 Feb 2015
Accepted
10 May 2015
First published
11 May 2015

Chem. Commun., 2015,51, 9666-9669

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A new lithium-rich anti-spinel in Li–O–Br system

J. Zhang, J. Zhu, L. Wang and Y. Zhao, Chem. Commun., 2015, 51, 9666 DOI: 10.1039/C5CC01109D

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