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Issue 28, 2015
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Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

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Abstract

Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s−1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.

Graphical abstract: Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

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Article information


Submitted
05 Feb 2015
Accepted
02 Mar 2015
First published
04 Mar 2015

Chem. Commun., 2015,51, 6172-6174
Article type
Communication

Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

C. J. Weiss, E. S. Wiedner, J. A. S. Roberts and A. M. Appel, Chem. Commun., 2015, 51, 6172
DOI: 10.1039/C5CC01107H

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