Issue 36, 2015

An intuitional hierarchical assembly of cluster–organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster

Abstract

An intuitional hierarchical assembly, metaphorically referred to as a “blossom and yield fruit” process, from a discrete cluster {[Co14(CH3O)4(dpbt)6Cl12]·14CH3OH, (1)} to 2D cluster organic frameworks {[Co14(CH3O)10(dpbt)6 Cl6]·12CH3OH, (2)}, has been established. The magnetic ordering of 2 was obviously improved compared with 1.

Graphical abstract: An intuitional hierarchical assembly of cluster–organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster

Supplementary files

Article information

Article type
Communication
Submitted
06 Feb 2015
Accepted
13 Mar 2015
First published
13 Mar 2015

Chem. Commun., 2015,51, 7598-7601

Author version available

An intuitional hierarchical assembly of cluster–organic frameworks with a thickness of 1.97 nm from a discrete Co14 cluster

F. Huang, P. Yao, H. Li, Q. Yu, H. Bian and H. Liang, Chem. Commun., 2015, 51, 7598 DOI: 10.1039/C5CC01057H

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